In an incident on 14.02.2014 in nuclear waste isolation pilot plant, cat litter containing organic matter used for stabilization of nuclear waste with nitrates, before storage, caused a chemical reaction generating heat and gases, bursting of lid off the drum and radiation leak. The temperature was at 1600 degrees (Celsius or Fahrenheit?) causing melting of plastic and rubber (from drums or nearby?). 22 workers were exposed to the incident but without any harmful effects. The cost of cleanup is estimated at USD 240 million.
As per practice, the cat litter with silicates is used for stabilization of the volatiles in the nuclear waste to prevent reaction with others. However changing the cat litter from clay based to organic based (corn/wheat) is suspected to have caused the exothermic reaction, failure of containment of the drum and radiation exposure.
We learnt about red oil explosion which can result from reaction of nitrates and organic and temperatures of above 135 deg C (generally) though it is possible at temperatures as low as 45-50 deg C.
We have to know many things before we do something. Definitely, this incident in New Mexico nuclear waste isolation plant is a clear case study for all of us to learn.
Please see the following links on the above incident.
http://www.theverge.com/2015/3/27/8299325/kitty-litter-nuclear-waste-accident-wipp
http://www.npr.org/blogs/thetwo-way/2014/05/23/315279895/organic-kitty-litter-chief-suspect-in-nuclear-waste-accident
http://www.telegraph.co.uk/news/worldnews/northamerica/usa/11499595/Wrong-kitty-litter-led-to-radiation-leak-at-New-Mexico-nuclear-waste-dump.html
http://www.santafenewmexican.com/special_reports/from_lanl_to_leak/lanl-officials-downplayed-waste-s-dangers-even-after-leak/article_54d7f3d2-8c99-5793-8c17-c4bdb0b72ef1.html?mode=jqm
http://www.currentargus.com/carlsbad-news/ci_25750452/doe-examining-possibility-kitty-litter-contributed-radiation-leak
http://www.livescience.com/50286-kitty-litter-to-blame-for-nuclear-waste-leak.html
2 page report:
http://energy.gov/sites/prod/files/2015/03/f20/TAT_Fact_sheet%2032615%20FINAL.pdf
277 page report on the incident:
http://energy.gov/sites/prod/files/2015/03/f20/MARCH%202015%20-%20FINAL%20TECHNICAL%20ASSESSMENT%20TEAM%20REPORT.pdf
http://www.santafenewmexican.com/special_reports/from_lanl_to_leak/lanl-officials-downplayed-waste-s-dangers-even-after-leak/article_54d7f3d2-8c99-5793-8c17-c4bdb0b72ef1.html?mode=jqm
http://www.currentargus.com/carlsbad-news/ci_25750452/doe-examining-possibility-kitty-litter-contributed-radiation-leak
http://www.livescience.com/50286-kitty-litter-to-blame-for-nuclear-waste-leak.html
2 page report:
http://energy.gov/sites/prod/files/2015/03/f20/TAT_Fact_sheet%2032615%20FINAL.pdf
277 page report on the incident:
http://energy.gov/sites/prod/files/2015/03/f20/MARCH%202015%20-%20FINAL%20TECHNICAL%20ASSESSMENT%20TEAM%20REPORT.pdf